科目名 Course Title 物質化学（固体物性化学） …This course deals with chemistry of solid-state materials, which are aggregates of molecules and atoms. The course aims

科目名 Course Title 物質化学（固体物性化学） [Materials Chemistry (Organic Solid State Chemistry)]

講義題目 Subtitle

責任教員 Instructor 原田潤 [Jun HARADA] (Faculty of Science)

担当教員 Other Instructors

開講年度 Year 2018 時間割番号Course Number 094201

期間 Semester Spring 単位数 Number of Credits 1

授業形態 Type of Class Lecture 対象年次 Year of Eligible Students ～

ナンバリングコード Numbering Code CHEM_ELMAT 6002

キーワード Key Words

molecular materials, crystal structures, symmetry, intermolecular interactions, charge-transfer interactions, hydrogen bonding, band structures,

electrical conductivity, solid-state reactions, molecular motions

授業の目標 Course Objectives

This course deals with chemistry of solid-state materials, which are aggregates of molecules and atoms. The course aims to enhance the

students' understanding of the relationship between intermolecular interactions and structures/functions/physical properties of molecular

crystals. The course provides perspectives as to how crystal and electronic structures of molecular materials are related to their physical

properties and how molecular motions and reactions in crystals can be understood in terms of crystal structures. It also introduces some of

advanced researches related to the topics.

到達目標 Course Goals

The goals of this course include:

- to understand principles by which molecular crystals are constructed.

- to understand the relationship between structural features of molecular crystals and their physical properties, molecular motions, and

reactivities.

- to acquire basic idea of functional material design: from molecular design to crystal design.

授業計画 Course Schedule

The following topics will be lectured in order:

1~2. Molecular structures and symmetry of crystals

The relationship between shapes of molecules and the structure/symmetry of their crystals will be discussed.

3~4. Intermolecular interactions and molecular arrangements in crystals

Influence of charge-transfer interaction and hydrogen bonding upon crystal structures will be discussed. Guidelines for controlling the

molecular arrangement will be presented.

5~6. Electronic states of molecular crystals

Electronic structure (band structure) of radical crystals will be discussed. Neutral-to-ionic transitions and formal charge of component

molecules will be explained.

7~8. Chemical reactions and molecular motions in crystals

Chemical reactions and molecular motions in crystals will be illustrated and explained in terms of the crystal structures.

準備学習（予習・復習）等の内容と分量 Homework

Students are expected to have basic knowledge of physical chemistry and need to review it beforehand. Reports will be assigned.

成績評価の基準と方法 Grading System

Unless under any special circumstances, more than 70% class attendance is required for the grade evaluation. The grade will be evaluated

according to the reports assigned during the course.

テキスト・教科書 Textbooks

必要に応じて資料を配付．

講義指定図書 Reading List

研究室のホームページ Website of Laboratory

http://barato.sci.hokudai.ac.jp/~kotai/kotai/HOME.html

備考 Additional Information

科目名 Course Title 物質化学（機能解析化学） [Materials Chemistry (Analysis of Physical Properties of Materials)]


責任教員 Instructor 武田定 [Sadamu TAKEDA] (Faculty of Science)



期間 Semester Fall 単位数 Number of Credits 1




Statistical mechanics, Magnetic susceptibility, Phase transition, Solid-state nuclear magnetic resonance, Molecular magnetism


Firstly, this course reviews basic concepts and methods of statistical dynamics, i.e. Boltzmann distribution, magnetic susceptibility, and phase

transition based on Ising model. Secondly, this course provides the skill of understanding principles of solid-state nuclear magnetic resonance

and magnetic interactions of nuclear spins, i.e. magnetic dipole interactions, nuclear quadrupole interactions, magnetic interaction between

nuclear spin and electron spin, which are important for understanding solid-state NMR spectrum.


Students are expected to understand the basic concepts and methods of solid-state nuclear magnetic resonance and to understand the

applications of the solid-state NMR for new materials, which appear in the literatures.


Session 1 (1 ~ 4) Instructor: Professor Takeda, Sadamu (Faculty of Science)

Basic concepts of statistical mechanics

1. Concept of probability

2. Statistical dynamics of two-levels system

3. Magnetic susceptibility

4. Ising model and phase transition

Session 2 (5 ~ 8) Instructor: Professor Takeda, Sadamu (Faculty of Science)

Solid-state nuclear magnetic resonance

1. Nuclear magnetic dipole interaction, molecular motion in the solid state and NMR spectrum

2. Nuclear quadrupole interaction, molecular motion in the solid state and NMR spectrum

3. Magnetic interactions between nuclear spin and electron spin and solid-state high-resolution NMR spectrum of molecular magnetic

compounds


Preparation for ATKINS’ Physical Chemistry 8th edition; chapter 15 (Molecular spectroscopy 3: magnetic resonance), Review and papers

according to instructor.


Final paper (75%), quiz and attendance attitude (25%)

Class participation more than 70% is required for grading



参照ホームページ Websites



Handout will be distributed

Students are requested to have basic knowledge of physical chemistry

科目名 Course Title 物質化学（ナノフォトニクス材料論） [Materials Chemistry (Nano-Photonics Materials)]


責任教員 Instructor 西井準治 [Junji NISHII] (Research Institute for Electronic Science)

担当教員 Other Instructors Hideo KAIJU(Research Institute for Electronic Science)


期間 Semester Summer 単位数 Number of Credits 1




Photonic Materials, Magnetic Materials, Photonic devices, Subwavelengh Optics, Plasmonics, Optical wave Analysis


The purpose of this lecture is to understand the relationships between functions and structures of several materials such as inorganic, metal

organic, composite. Especially, this lecture focuses on the fabrication and analysis of photonics materials and their applications to information

network and digital appliances.


1. Fundamental studies on electronic structures, photonic functions, magnetic functions and their analysis.

2. Fundamental studies on electronic structures, interactions between photon and electron, optical wave propagation, and magnetism for a

comprehensive understanding on oxide-based photonics materials and metal-based magnetic materials.


This lecture will review the photonics materials, the device applications, and the engineering innovations in the advanced information society:

(1) Photonics materials and magnetic materials,

(2) Fundamentals on refraction, diffraction, and interference,

(3) Optical communication devices and materials using optical diffraction,

(4) Photonics devices using optical phase,

(5) Plasmonics and its application for analysis.

(6) Optics and electron spin

(7) Fundamentals of magnetic materials

(8) Spintronics and its application


The outline can be understood from the delivered documents in each lecture. The report works will be given at an end of each section.


The academic results will be determined based on the attendance and reports.



光エレクトロニクス入門／西原浩、裏升吾：コロナ社

第二版応用光学光計測入門／谷田貝豊彦：丸善

回折光学入門／応用物理学会日本光学会光設計研究グループ監修：オプトロニクス社

強磁性体の物理（上）／近角聡信：裳華房


http://www.es.hokudai.ac.jp/


http://nanostructure.es.hokudai.ac.jp/eng/index.html


科目名 Course Title 物質化学Ａ（無機固体化学） [Materials Chemistry A (Inorganic Solid State Chemistry)]


責任教員 Instructor 日夏幸雄 [Yukio HINATSU] (Faculty of Science)

担当教員 Other Instructors Makoto WAKESHIMA(Faculty of Science), Yoshihiro DOI(Faculty of Science)






solid state chemistry, magnetic properties, electronic properties


This course offers systematic knowledge about the relationship between structures of solid materials and their physical properties. Basic

knowledge about the synthesis of inorganic compounds, determination of their crystal structures and magnetic and electronic properties will be

presented.


Students will learn the basic theory and application of various kinds of physical property measurements, and understand the relationship between

the structures of solid materials and their physical properties.


1. Structure analysis by X-ray and neutron diffraction methods

1.1 order-disorder transition

1.2 magnetic structure

2. Magnetic properties of solids

2.1 Origin of magnetism

2.2 Magnetism of ferrites

2.3 Magnetization and hysteresis of ferromagnetic materials

3. Mossbauer spectroscopy

3.1 Basic theory

3.2 Applications

4. Current research trends in solid state chemistry

5. Examination


Students are expected to review every lecture.


Class participation and examination.


Handouts made by the instructor will be delivered.


大学院無機化学（上）／岩本振武ら：講談社，1992

希土類とアクチノイドの化学／Simon Cotton：丸善，2008




科目名 Course Title 物質化学Ａ（ナノ物質化学） [Materials Chemistry A (Mesoscopic Material Chemistry)]


責任教員 Instructor 佐田和己 [Kazuki SADA] (Faculty of Science)

担当教員 Other Instructors Akira KAKUGO(Faculty of Science)


期間 Semester Spring/Summer 単位数 Number of Credits 2




Self-organization, Molecular Networks, Molecular Machine, Molecular Assembly, Supramolecular Chemistry, Gel, Nanoporous Materials,

Crystals, Kinesin, Myosin, Dynein


Self-organization and complex system are key concepts for designing structure and function of materials. This course will provide fundamentals

of self-organization from two different viewpoints; supramolecular chemistry and biomaterials. In particular, it is divided into two topics; (I)

molecular networks and (II) bio-molecular machines.

(I) Molecular Networks

The first part will focus on construction and properties of molecular-level network structures; lattice inclusion compounds, porous coordination

polymers, polymer gels, organo- or hydrogels from low-molecular-weight gelators. Some applications of all these materials such as separation,

catalysis, storage will be given.

(II) Bio-Molecular Machines

The latter part will be offered for students who want to learn about the system of bio-molecular machines. In this course, students will get a

chance to come to know about: (1) basic information on bio-molecular machines and their working principle, (2) integration mechanism of bio-

molecular machines into highly organized structure, (3) correlation between the structure and dynamic property. Furthermore, this course will

focus on industrial applications of bio-molecular machines by way of making use of genetic engineering technique and nano-biotechnology.


Firstly this course reviews fundamentals of molecular network structures and bio-molecular machines with respect to self-organization.

Students will be able to acquire basic knowledge both on preparation and molecular design of network structures and on bio-molecular machines,

understand their construction and working principle in advanced applications of physical chemistry and material science.


(Topic I) Molecular Networks provided by K. S.

1. Introductory for Molecules, Informations, and Self-Organization

2. Lattice Inclusion Crystals: Organic Self-assembled System

3. Macrocyclic Compounds as Host Compounds

4. Zeolite and Related Inorganic Nanoporous Materials

5. Metal-Organic Frameworks as the third Generation

6. Chemically-crosslinked Gels

7. Physical Gels including Low-Molecular-Weight Organogels

(Topic II) Bio-Molecular Machines by A. K.

1. Introduction to bio-molecular machine

2. Generation mechanism of energy (ATP) through photo-synthesis

3. Self-organization of bio-molecular machine

4. Working principle and industrial application of bio-molecular machine


Students will read reviews and the primary literature on each topic, and submit questions for instrutor after every classes and some written

reports on the topics.


Attendance more than 70% classes is requisite for evaluation of the credit. The grade is evaluated in the following three items;(1) learning

attitude (30%), (2) report (10%), (3) examination or paper (60%). Understanding for each class is evaluated by report, and the basic knowledge

for the subject is by term examination or paper.






科目名 Course Title 応用物質化学（有機物性化学） [Applied Materials Chemistry (Physical Chemistry of Organic Materials)]


責任教員 Instructor 小泉均 [Hitoshi KOIZUMI] (Faculty of Engineering)







polymers, glass transition, rubber elasticity, viscoelasticity, creep, stress relaxation, Time-temperature superposition principle, weather

resistance of polymers


Mechanical properties of polymers and their dependence on the molecular structure, temperature and time are taught. The mechanisms of the

fracture and chemical deterioration of polymers are also taught. The aims of this course are to understand characteristic properties of polymers

and the relationship between durability of polymers and their chemical and physical structures.


The goals of this course are to understand characteristic properties of polymers, such as rubber elasticity, and viscoelasticity, and to get

fundamental knowledge for developing novel polymer materials or using polymer materials.


The lectures about the following subjects and short tests after the lectures are given. The lesson plan: 1. Characteristics of polymers, 2. Rubber

elasticity, 3. Dependence of elasticity of polymers on their structures, 4. Viscoelasticity, 5. Time-temperature superposition principle, 6.

Stress-strain behavior and strength of polymers, 7. Weather resistance of polymers, 8. Final examination.


Review the lessons with distributed handouts.


The grade is given with the sum of 30 % of the average score of the short tests and 70% of the score of the final examination.


教科書は用いない。毎回，Lecture 内容をまとめたプリントを配付する。





科目名 Course Title 応用物質化学（界面電子化学） [Applied Materials Chemistry (Interfacial Electrochemistry)]


責任教員 Instructor 伏見公志 [Koji FUSHIMI] (Faculty of Engineering)







Electrode structure, interfacial reaction, charge transfer process, mass transport process, electrochemical methods，micro-electrochemistry


The reactions occurring at interfaces between electrolyte and materials, i.e., electrodes are discussed. Students learn electrode reactions from

views of interfacial thermodynamics, charge transfer kinetics, and mass transport process at the interface. They then proceed to principle and

application using electrochemical methods as well as physical chemistry at the interface.


Discussions start from basic aspects of electrochemistry, mainly for electrode structure including atomic level surface, electric double layer,

electrode potential, etc. and are extended to interfacial reaction such as charge transfer process and mass transfer process. The goal of this

course is supply details of electrochemical methods both to evaluate and to apply electrochemical reaction. Students are finally required to

present and discuss electrochemical or interfacial subjects as well as their own research subjects.


1-3. Fundamentals of electrochemistry; electrode structure, electrode potential, non-Faradaic and Faradaic processes, energy conversion,

electrolyte

4. Outline of electrochemical methods; apparatus, electrochemical cell, and electric circuit used in electrochemistry

5-6. Polarization technique; controlling processes of interfacial reaction (charge transfer process and mass transfer process), cyclic

voltammetry，hydrodynamic method, microelectrode technique

7. Transient technique; potentiometry, ammerometry, coulometry, AC impedance spectroscopy, electrochemical sensor

8. Presentation; electrochemical theory and methods in newest research topics are introduced and discussed.


Students are requested to read relevant contents in the textbook beforehand. Students are also expected to study recent journal articles in

interfacial electrochemistry and prepare presentation materials to be used in class discussions.


Presentations(50%) and reports(50%)


Electrode Dynamics／A.C. Fisher：Oxford University Press，1996


電気化学測定法（上）／藤嶋昭,相澤益男,井上徹：技報堂出版，1984

Electrochemical Methods, Fundamentals and Applications, 2nd ed.／Allen J. Bard, Larry R. Faulkner：Wiely，2001

Analytical and Physical Electrochemistry／Hubert H. Girault：EPFL Press


http://www.eng.hokudai.ac.jp/labo/amc/6.lectures/fushimi-file/i-elechem.html


http://www.eng.hokudai.ac.jp/labo/amc/index.html


科目名 Course Title 応用物質化学（無機物性化学） [Applied Materials Chemistry (Inorganic Solid State Chemistry)]


責任教員 Instructor 鱒渕友治 [Yuji MASUBUCHI] (Faculty of Engineering)







Sintering, Thin film, Single crystal, Nano materials, Morphology


Inorganic solids are known to show various properties depending on their constituent elements and crystal structure. Additionally, from the

viewpoint of “material” their morphology and microstructure must be optimized to achieve their applications. This lecture will be dealing with

preparation process of sintered body, thin film, single crystal, and nano materials for inorganic materials. We will also discuss how their physical

properties relate to their morphology and micro structure.


To understand a relationship between various properties and microstructure. To learn preparation methods of sintered body, thin film, single

crystal, and nano materials. To understand fundamental mechanism of diffusion, nucleation, crystal growth, and grain growth.


1. Introduction: properties and morphology of inorganic solids

2. Sintering: solid and liquid phase diffusion, sintering of metal nitrides

3. Thin film: deposition process, vacuum deposition, vapor and liquid phase deposition

4. Single crystal: crystal growth mechanism, various crystal growth process

5. Nano material: properties, nano particles, composites, assemblage


Students are encouraged to read the handouts which will be given prior to each class.


Examination 30% (on each lecture) and final report 70%


適宜、資料を配付する。



http://www.eng.hokudai.ac.jp/labo/strchem/lectures.html



科目名 Course Title 応用物質化学（電子材料化学特論） [Applied Materials Chemistry (Physical Chemistry of Electronic

Materials)]


責任教員 Instructor 青木芳尚 [Yoshitaka AOKI] (Faculty of Engineering)



期間 Semester Winter 単位数 Number of Credits 1




Fuel cells, semiconductors, ion conductors, heterojunctions, defect thermodynamics


solid state electrochemical devices


Fundamentals of fuel cells and related electrochemical devices.

To understand the phenomena at solid electrolyte-electrode interfaces.

Band structures at meta/semiconductor hetero junctions.

Interplays between ion and electron carriers in solid state electrolytes.


1. Introduction of band theory

2. Correlation between catalytic activity and electronic properties of Pt ORR catalysts.

3. PCFC and SOFC

4. Relationship between solid solid interfacial properties and electrochemical reaction.s

5. Novel solid state energy devices based on the interplays between ion and electron carriers.


To understand the basics of Fuel cells. Concepts of electrode reactions and overpotentials at batteries.


Scores of final reports


Physics of semiconductor devices／S. M. Sze

電極化学上／佐藤教男





科目名 Course Title 応用物質化学Ａ（機能固体化学） [Applied Materials Chemistry A (Solid State Chemistry of Functional

Materials)]


責任教員 Instructor 島田敏宏 [Toshihiro SHIMADA] (Faculty of Engineering)

担当教員 Other Instructors Taro NAGAHAMA(Faculty of Engineering)


期間 Semester Fall/Winter 単位数 Number of Credits 2




First part (3rd semester):

-Interface, thin film, crystal growth, nanojunction, spintronics, magnetism, electronic devices -

Second part (4th semester):

-Structure and functions of solid state materials -

-Ligand field theory, semiconductors, solar cells, lasers, non-linear optics, phase transition kinetics, electron correlation, ultra hard ceramics,

plasmonics, superconductivity etc.



Study the electronic and magnetic properties of thin films and nanostructured materials. Several fabrication methods, i.e. MBE, sputtering,

PLD are introduced. The relation between the function of the nano-materials and electronic states and magnetism will be explained.

Second part (4th semester)

Study the relationship between the structure and function of solid state materials.

Obtain deep insights in the atomic scale about the chemistry and physics behind the practical technologies, such as magnet, solar cells, lasers,

thermal camera and CD-R/W.



Learn the electronic states in the solid state materials; band structure and magnetic interactions. Understand the development of the new

functional devices and fabrication process.


The goal is to understand the "heart" of chemistry and physics of solid state functional materials and obtain the ability to design and crate new

materials. The lecture and the homeworks will be organized to achieve this goal.



1. outline of the nanostructured materials and thin films

2-4 electronic states in solid; band theory.

5-6 magnetic properties of solid

7 fabrication process of nan-structure and thin films

8 development of the devices: spintronics


Topics other than the list can also be lectured according to request.

1. Introduction to solid state chemistry / physics and thermoelectricity

2. semiconductors focused on solar cells

3. transparent conductors (oxides, nanowires, graphene)

4. advanced ligand field theory and basics of photophysics - lasers,

nonlinear optics, optical fibers

5. interfaces: workfunction and chemistry of semiconductor junction devices

6. phase memory materials (DVD-R/W, shape memory alloys)

7．ferroelectrics and shape memory alloy

8. thermography and strongly correlated electron systems


Preparation: read the handout posted on the website (URL will be given at the first lecture).

Review: solve the problem given in the lecture and write brief reports.


Grading is based on the quiz given at each lecture and the final report.



Inorganic chemistry／D.F. Shriver and P.W. Atkins：Oxford University Press，2006

上記は購入する必要はない。配布プリントを使用する。

No need to purchase the book. We use handouts.



www.eng.hokudai.ac.jp/labo/kotai


科目名 Course Title 応用物質化学Ａ（応用材料化学) [Applied Materials Chemistry A (Applied Inorganic Materials

Chemistry)]


責任教員 Instructor 忠永清治 [Kiyoharu TADANAGA] (Faculty of Engineering)

担当教員 Other Instructors Tetsuo UCHIKOSHI(NIMS), Takashi TAKEDA(NIMS), Katsuya KATO(AIST), Norihito KIJIMA(AIST)






Nanoparticle, nano- and meso-porous materials, Functional inorganic material, Bio-ceramic composites, Bulk material, Materials processing,

Nanostructural analysis, Functional characterization


The relation between the functionality of materials, especially inorganic functional materials, and their electronic state, nanostructure and

macroscopic form such as bulk will be lectured. The appearance mechanism of various functionality obtained by controlling the composition

and microstructure of the materials, the processing methods of functionality-designed materials and the characterization techniques of the

materials will be addressed. The prospects for industrial application in the future will be discussed by taking up some topics, including the

synthesis of nanoparticles and nanocomposites, the synthesis of nano-porous oxides and nano-porous oxide-biomolecule composites, and the

synthesis of electrode materials for lithium ion batteries.


The relation between the materials properties and nano/micro-structures drawing the required functions to the maximum will be understood.

In addition, the basic science and skills for materials processing and analysis will be mastered. The task to find a topic for oneself and investigate

it will be given to the students as training to select and treat information scientifically.


Lectures will be given by Professor Tetsuo UCHIKOSHI, Professor Takashi TAKEDA (NIMS)，Professor Katsuya KATO and Professor

Norihito KIJIMA (AIST).

The following contents will be lectured using the documents edited for the class by the lecturers:

1.Introduction: Structure and functionality of nanomaterials.

2.Processing technique: Powder synthesis via gas, liquid or solid phase reaction and processing chemistry of bulk materials.

3.Property and characterization: Characterization of particle and powder, nano-micro-macro structure of bulk materials. Evaluation of electric,

electrochemical, magnetic, optical, mechanical and catalytic properties.

4.Summary: Industrial application and future prospects of nanoscience and nanotechnology. Role and the possibility of nanomaterials in the

sustainable society.


Review the distributed documents and blackboard demonstration contents, and ask any questions at the next class.


Your attitude in classes (20%) and reports (80%) will affect your final grade.


なし。適宜資料を配布する。



http://www.nims.go.jp/, http://www.aist.go.jp/



Some documents will be distributed if necessary.

Documents

科目名 Course Title 物質化学（固体物性化学） …This course deals with chemistry of solid-state materials, which are aggregates of molecules and atoms. The course aims