KI1101-2012-KD Lec06c Gases

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    Contents

    *- Properties of &ases+ &as Pressure*-2 #he "iple &as )a.s

    *-/ Coinin1 the &as )a.s+

    #he !deal &as Euation and#he &eneral &as Euation

    *-3 (pplications of the !deal &as Euation

    *-4 &ases in Cheical $eactions*-* i5tures of &ases

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    Contents

    *-* i5tures of &ases*-7 6ineticolecular #heory of &ases

    *-8 &as Properties $elatin1 to the

    6ineticolecular #heory

    *-9 'onideal :$eal; &ases

    Focus On Earths Atmosphere

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    #he 1aseous states of three halo1ens

    P> ? constant

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    Relating Gas Volume and Pressure Boyles Law. #he

    volue of a lar1e irre1ularly shaped, closed tan can edeterined< #he tan is first evacuated and then connected to a

    40

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    EXAMPLE 6-4

    P>? P2>2 >2? P>P2

    ? *93 ) >tan? *33 )

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    CharlesFs )a.

    Charles 787&ay-)ussac 802

    > # > ? #

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    "tandard #eperature and Pressure

    &as properties depend on conditionsflas? H2=dH2= ? :/8

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    Use the Gas Equation:

    P> ? n$# P> ?

    $# ?

    P>$#

    ?:0

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    &as Densities

    P> ? n$# and d ? >

    P>?

    $#

    P

    $#>

    ? d ?

    , n ?

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    *-4 &ases in Cheical $eactions

    "toichioetric factors relate 1as uantities to

    uantities of other reactants or products'

    /P

    2u

    umis the odal speed

    uavis the siple avera1e

    urms

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    Pressure

    /$#u

    u/$#

    u-$#/

    u-/

    ,

    P>

    r-s

    2

    2

    (

    2(

    (ssue one ole+

    P>?$# so+

    $ ? +

    $earran1e+

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    Distriution of olecular "peeds

    /$#u r-s

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    Deterinin1 olecular "peed

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    #eperature

    :#;$

    2

    /e

    e

    /

    2$#

    ;u-2

    ,:/

    2u-/

    ,P>

    (

    22

    (

    $

    $

    odify+

    P>?$# so+

    "olve for e+

    (vera1e inetic ener1y is directly proportional to teperatureQ

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    *-8 &as Properties $elatin1 to the

    6inetic-olecular #heory

    Diffusion

    'et rate is proportional toolecular speed