Réactions d’ordre 1 ou

Ractions dordre 1ou

Ractions dordre 1ou temps de demi-raction

exemple 0

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

t(s)[A] (M)ln([A]/[A]_0)

050002.320.00

1003.550.08169014088.16901408454001.72-0.30

2002.750.163636363616.36363636368001.3-0.58

3002.250.244444444424.444444444412000.98-0.86

4001.850.340540540534.054054054116000.73-1.16

6001.480.475675675747.567567567620000.54-1.46

t(s)

[A](mole/L)

t(s)

1/[A]-1/[A]_0 (M-1)

t(s)

ln(A/A_0)

Chart6

0

-0.2992428949

-0.5792029212

-0.861769893

-1.1562779305

-1.4577533251

t(s)

ln(A/A_0)

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

t(s)[A] (M)ln([A]/[A]_0)

050002.320.00

1003.550.08169014088.16901408454001.72-0.30

2002.750.163636363616.36363636368001.3-0.58

3002.250.244444444424.444444444412000.98-0.86

4001.850.340540540534.054054054116000.73-1.16

6001.480.475675675747.567567567620000.54-1.46

t(s)

[A](mole/L)

t(s)

1/[A]-1/[A]_0 (M-1)

t(s)

ln(A/A_0)

exemple 1

t(s)PAx102 (mmHg)ln(PA/PA,0)

08,2010005,7220003,9930002,7840001,94

exemple 1

t(s)PAx102 (mmHg)ln(PA/PA,0)08,200,010005,72-0,35920003,99-0,71930002,78-1,0840001,94-1,44

Chart1

0

-0.359

-0.719

-1.08

-1.44

t(s)

ln[P_A/P_A(0)]

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

Sheet3

Ractions dordre 2ou

Ractions dordre 2ou temps de demi-raction

exemple 2

t(min)[C2H6](mol/l)1/[C2H6]- 1/[C2H6]0(mol/l)00,0169012,180,014410,324,550,012421,542,500,010337,968,050,008558,5

exemple 2

t(min)[C2H6](mol/l)1/[C2H6]- 1/[C2H6]0(mol/l)00,0169012,180,014410,324,550,012421,542,500,010337,968,050,008558,5

Chart2

0

10.2728468113

21.4735636572

37.9157810076

58.4754611904

t(min)

1/[A]-1/[A]_0

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

exemple 3ordre ?

t(s)0100200300400600100[A] (M)5,003,552,752,251,851,48

Chart3

5

3.55

2.75

2.25

1.85

1.48

t(s)

[A](mole/L)

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

050

1003.550.0816901408

2002.750.1636363636

3002.250.2444444444

4001.850.3405405405

6001.480.4756756757

t(s)

[A](mole/L)

exemple 3

t(s)0100200300400600100[A] (M)5,003,552,752,251,851,48

Chart3

5

3.55

2.75

2.25

1.85

1.48

t(s)

[A](mole/L)

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

050

1003.550.0816901408

2002.750.1636363636

3002.250.2444444444

4001.850.3405405405

6001.480.4756756757

t(s)

[A](mole/L)

exemple 3ordre =2

t(s)0100200300400600100[A] (M)5,003,552,752,251,851,48

Chart3

5

3.55

2.75

2.25

1.85

1.48

t(s)

[A](mole/L)

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

050

1003.550.0816901408

2002.750.1636363636

3002.250.2444444444

4001.850.3405405405

6001.480.4756756757

t(s)

[A](mole/L)

exemple 3

t(s)01002003004006001/[A]-1/[A]0 (M-1)5,003,552,752,251,851,48

Chart4

0

8.1690140845

16.3636363636

24.4444444444

34.0540540541

47.5675675676

t(s)

1/[A]-1/[A]_0 (M-1)

Sheet1

08.20

10005.72-0.359

20003.99-0.719

30002.78-1.08

40001.94-1.44

Sheet1

t(s)

ln[P_A/P_A(0)]

Sheet2

00.01690

12.180.014410.2728468113

24.550.012421.4735636572

42.50.010337.9157810076

68.050.008558.4754611904

Sheet2

t(min)

1/[A]-1/[A]_0

Sheet3

t(min)

[A]

0500

1003.550.08169014088.1690140845

2002.750.163636363616.3636363636

3002.250.244444444424.4444444444

4001.850.340540540534.0540540541

6001.480.475675675747.5675675676

t(s)

[A](mole/L)

t(s)

1/[A]-1/[A]_0 (M-1)

Ractions dordre n>2ou

Autres: raction dordre 2

Ractifs en proportions non stoechiomtriques


Ractifs en proportions non stoechiomtriques??


Ractifs en proportions non stoechiomtriquesdfini pour A et B sparment


Ractifs en proportions stoechiomtriques

Dtermination des ordres partiellesmthode disolation (dilution) dOswaldmthode de la vitesse initiale

mthode de la vitesse initialeExemple 1

Expt.[S2O82-] (M)[I-](M)V0(M.s-1)10,0380,0601,4x10-520,0760,0602,8x10-530,0760,0301,4x10-5

mthode de la vitesse initialeExemple 2

[OH-](M)[OCl-] (M)[I-](M)V0(M.s-1)1,000,0040,0024,8x10-40,500,0020,0024,6x10-40,250,0020,0029,4x10-41,000,0020,0045,0x10-41,000,0020,0022,4x10-4

Documents

Réactions d’ordre 1 ou