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Tp de Cristallochimieeeee (1)

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UNIVERSITE MOHAMMED V Groupe B02Facult des Sciences -Anouar jebraouDpartement de Chimie -Mehdi hsinatRabat

Caracterisation dune solution solide par diffraction des rayons XPour KUP:CYCLE NUMERO 2 1 1 0 17.9200 17.9219 -0.0019 4.9458 4.9453 0 0 2 20.4200 20.4213 -0.0013 4.3456 4.3453 1 0 2 24.0900 24.0921 -0.0021 3.6912 3.6909 2 0 0 25.4500 25.4509 -0.0009 3.4970 3.4968 1 1 2 27.3000 27.2985 0.0015 3.2640 3.2642 2 1 1 30.3500 30.3471 0.0029 2.9426 2.9429 2 0 2 32.8500 32.8487 0.0013 2.7241 2.7243 2 1 2 35.3300 35.3291 0.0009 2.5384 2.5385 2 2 0 36.3000 36.3020 -0.0020 2.4728 2.4726 ecart-type 0.0020 0.0020 delta 2 theta moyen 0.0016 RESULTAT DU CYCLE 6.9937 0.0000 6.9937 0.0002 6.9937 0.0000 6.9937 0.0002 8.6906 0.0000 8.6906 0.0005 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 8.691 10.17 10.17 1 0 0 6.994 12.65 12.65 1 0 1 5.449 16.25 16.25 1 1 0 4.945 17.92 17.92 0 0 2 4.345 20.42 20.42 1 1 1 4.298 20.65 20.65 1 0 2 3.691 24.09 24.09 2 0 0 3.497 25.45 25.45 1 1 2 3.264 27.30 27.30 2 0 1 3.244 27.47 27.47 2 1 0 3.128 28.51 28.51 2 1 1 2.943 30.35 30.35 0 0 3 2.897 30.84 30.84 2 0 2 2.724 32.85 32.85 1 0 3 2.676 33.45 33.45 2 1 2 2.538 35.33 35.33 1 1 3 2.500 35.90 35.90 2 2 0 2.473 36.30 36.30 2 2 1 2.378 37.80 37.80 3 0 0 2.331 38.59 38.59

Pour k0.8Rb0.2UP:CYCLE NUMERO 3 1 1 0 17.9100 17.9127 -0.0027 4.9485 4.9478 0 0 2 20.2200 20.2222 -0.0022 4.3881 4.3876 1 0 2 23.9200 23.9186 0.0014 3.7171 3.7173 2 0 0 25.4400 25.4377 0.0023 3.4983 3.4986 1 1 2 27.1400 27.1411 -0.0011 3.2829 3.2828 2 1 1 30.3000 30.2988 0.0012 2.9473 2.9475 2 0 2 32.7100 32.7104 -0.0004 2.7355 2.7355 2 1 2 35.2000 35.1969 0.0031 2.5475 2.5477 2 2 0 36.2800 36.2828 -0.0028 2.4741 2.4739 ecart-type 0.0024 0.0024 delta 2 theta moyen 0.0019 RESULTAT DU CYCLE 6.9972 -0.0000 6.9972 0.0003 6.9972 -0.0000 6.9972 0.0003 8.7753 0.0000 8.7753 0.0006 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 8.775 10.07 10.07 1 0 0 6.997 12.64 12.64 1 0 1 5.471 16.19 16.19 1 1 0 4.948 17.91 17.91 0 0 2 4.388 20.22 20.22 1 1 1 4.310 20.59 20.59 1 0 2 3.717 23.92 23.92 2 0 0 3.499 25.44 25.44 1 1 2 3.283 27.14 27.14 2 0 1 3.250 27.42 27.42 2 1 0 3.129 28.50 28.50 2 1 1 2.947 30.30 30.30 0 0 3 2.925 30.54 30.54 2 0 2 2.735 32.71 32.71 1 0 3 2.699 33.17 33.17 2 1 2 2.548 35.20 35.20 1 1 3 2.518 35.63 35.63 2 2 0 2.474 36.28 36.28 2 2 1 2.381 37.75 37.75 3 0 0 2.332 38.57 38.57 3 0 1 2.254 39.96 39.96

Pour K0.6Rb0.4UP:CYCLE NUMERO 3 1 1 0 17.9000 17.9050 -0.0050 4.9513 4.9499 0 0 2 20.0300 20.0289 0.0011 4.4293 4.4295 1 0 2 23.7500 23.7511 -0.0011 3.7433 3.7431 2 0 0 25.4300 25.4267 0.0033 3.4997 3.5001 1 1 2 26.9900 26.9898 0.0002 3.3008 3.3008 2 1 1 30.2500 30.2541 -0.0041 2.9521 2.9517 2 0 2 32.5800 32.5784 0.0016 2.7461 2.7462 2 1 2 35.0700 35.0712 -0.0012 2.5566 2.5565 2 2 0 36.2700 36.2669 0.0031 2.4747 2.4749 ecart-type 0.0031 0.0031 delta 2 theta moyen 0.0023 RESULTAT DU CYCLE 7.0002 0.0000 7.0002 0.0004 7.0002 0.0000 7.0002 0.0004 8.8591 0.0000 8.8591 0.0009 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 8.859 9.98 9.98 1 0 0 7.000 12.63 12.63 1 0 1 5.492 16.12 16.12 1 1 0 4.950 17.90 17.90 0 0 2 4.430 20.03 20.03 1 1 1 4.321 20.54 20.54 1 0 2 3.743 23.75 23.75 2 0 0 3.500 25.43 25.43 1 1 2 3.301 26.99 26.99 2 0 1 3.255 27.38 27.38 2 1 0 3.131 28.49 28.49 0 0 3 2.953 30.24 30.24 2 1 1 2.952 30.25 30.25 2 0 2 2.746 32.58 32.58 1 0 3 2.721 32.89 32.89 2 1 2 2.557 35.07 35.07 1 1 3 2.536 35.36 35.36 2 2 0 2.475 36.27 36.27 2 2 1 2.384 37.71 37.71 3 0 0 2.333 38.55 38.55 2 0 3 2.257 39.91 39.91 3 0 1 2.256 39.92 39.92Pour K0.4Rb0.6UP:

CYCLE NUMERO 3 1 1 0 17.9000 17.8966 0.0034 4.9513 4.9522 0 0 2 19.8400 19.8409 -0.0009 4.4713 4.4711 1 0 2 23.5900 23.5883 0.0017 3.7683 3.7686 2 0 0 25.4100 25.4147 -0.0047 3.5024 3.5017 1 1 2 26.8400 26.8425 -0.0025 3.3189 3.3186 2 1 1 30.2100 30.2096 0.0004 2.9559 2.9560 2 0 2 32.4500 32.4496 0.0004 2.7568 2.7568 2 1 2 34.9500 34.9483 0.0017 2.5651 2.5652 2 2 0 36.2500 36.2495 0.0005 2.4761 2.4761 ecart-type 0.0026 0.0026 delta 2 theta moyen 0.0018 RESULTAT DU CYCLE 7.0034 -0.0000 7.0034 0.0003 7.0034 -0.0000 7.0034 0.0003 8.9421 -0.0000 8.9421 0.0007 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 8.942 9.88 9.88 1 0 0 7.003 12.63 12.63 1 0 1 5.514 16.06 16.06 1 1 0 4.952 17.90 17.90 0 0 2 4.471 19.84 19.84 1 1 1 4.332 20.48 20.48 1 0 2 3.769 23.59 23.59 2 0 0 3.502 25.41 25.41 1 1 2 3.319 26.84 26.84 2 0 1 3.261 27.33 27.33 2 1 0 3.132 28.47 28.47 0 0 3 2.981 29.95 29.95 2 1 1 2.956 30.21 30.21 2 0 2 2.757 32.45 32.45 1 0 3 2.743 32.62 32.62 2 1 2 2.565 34.95 34.95 1 1 3 2.554 35.11 35.11 2 2 0 2.476 36.25 36.25 2 2 1 2.386 37.66 37.66 3 0 0 2.334 38.53 38.53 2 0 3 2.270 39.68 39.68 3 0 1 2.259 39.88 39.88Pour k0.2Rb0.8UP:CYCLE NUMERO 3 1 1 0 17.8900 17.8866 0.0034 4.9540 4.9549 0 0 2 19.6600 19.6591 0.0009 4.5118 4.5120 1 0 2 23.4300 23.4303 -0.0003 3.7937 3.7936 2 0 0 25.4000 25.4004 -0.0004 3.5037 3.5037 1 1 2 26.7000 26.6992 0.0008 3.3360 3.3361 2 1 1 30.1600 30.1637 -0.0037 2.9607 2.9604 2 0 2 32.3200 32.3234 -0.0034 2.7676 2.7673 2 1 2 34.8300 34.8274 0.0026 2.5737 2.5739 2 2 0 36.2300 36.2287 0.0013 2.4774 2.4775 ecart-type 0.0026 0.0026 delta 2 theta moyen 0.0019 RESULTAT DU CYCLE 7.0073 -0.0000 7.0073 0.0003 7.0073 -0.0000 7.0073 0.0003 9.0240 -0.0000 9.0240 0.0007 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 9.024 9.79 9.79 1 0 0 7.007 12.62 12.62 1 0 1 5.535 16.00 16.00 1 1 0 4.955 17.89 17.89 0 0 2 4.512 19.66 19.66 1 1 1 4.343 20.43 20.43 1 0 2 3.794 23.43 23.43 2 0 0 3.504 25.40 25.40 1 1 2 3.336 26.70 26.70 2 0 1 3.266 27.28 27.28 2 1 0 3.134 28.46 28.46 0 0 3 3.008 29.67 29.67 2 1 1 2.960 30.16 30.16 2 0 2 2.767 32.32 32.32 1 0 3 2.764 32.36 32.36 2 1 2 2.574 34.83 34.83 1 1 3 2.571 34.86 34.86 2 2 0 2.477 36.23 36.23 2 2 1 2.389 37.62 37.62 3 0 0 2.336 38.51 38.51 2 0 3 2.282 39.45 39.45 3 0 1 2.261 39.83 39.83 0 0 4 2.256 39.93 39.93Pour RbUP:CYCLE NUMERO 2 1 1 0 17.8900 17.8863 0.0037 4.9540 4.9550 0 0 2 19.6600 19.6861 -0.0261 4.5118 4.5059 1 0 2 23.4300 23.4531 -0.0231 3.7937 3.7900 2 0 0 25.4000 25.3999 0.0001 3.5037 3.5037 1 1 2 26.7000 26.7193 -0.0193 3.3360 3.3336 2 1 1 30.1600 30.1677 -0.0077 2.9607 2.9600 2 0 2 32.3200 32.3401 -0.0201 2.7676 2.7659 2 1 2 34.8300 34.8429 -0.0129 2.5737 2.5728 2 2 0 36.2300 36.2280 0.0020 2.4774 2.4775 2 0 3 39.5500 39.4817 0.0683 2.2767 2.2805 ecart-type 0.0294 0.0294 delta 2 theta moyen 0.0183 RESULTAT DU CYCLE 7.0075 0.0000 7.0075 0.0034 7.0075 0.0000 7.0075 0.0034 9.0118 0.0000 9.0118 0.0071 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 90.0000 0.0000 H K L D 2 *THETA 2 *THETA CORR 0 0 1 9.012 9.81 9.81 1 0 0 7.007 12.62 12.62 1 0 1 5.532 16.01 16.01 1 1 0 4.955 17.89 17.89 0 0 2 4.506 19.69 19.69 1 1 1 4.342 20.44 20.44 1 0 2 3.790 23.45 23.45 2 0 0 3.504 25.40 25.40 1 1 2 3.334 26.72 26.72 2 0 1 3.266 27.29 27.29 2 1 0 3.134 28.46 28.46 0 0 3 3.004 29.72 29.72 2 1 1 2.960 30.17 30.17 2 0 2 2.766 32.34 32.34 1 0 3 2.761 32.40 32.40 2 1 2 2.573 34.84 34.84 1 1 3 2.569 34.90 34.90 2 2 0 2.478 36.23 36.23 2 2 1 2.389 37.62 37.62 3 0 0 2.336 38.51 38.51 2 0 3 2.281 39.48 39.48 3 0 1 2.261 39.83 39.83 0 0 4 2.253 39.99 39.99