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    Heat Engines

    Refrigerators

    Heat Pumps

    Heat Engine (Carnots engine)

    Heat engines operate in a cycle, converting heat to work then returning to original state at end ofcycle. Consider a machine placed between a high and low T reservoir. Heat is absorbedreversibly from TH and discharged to Tc by the machine. A machine is assumed a steady statedevice in this case. (U=0, S=0). As the machine works in reversible manner hence lw=0. For aclosed system under steady state, first law can be written

    Q+ Wrev=0

    QH+ QL + Wrev=0 (1)

    Also as per 2nd law

    Q/T=0

    QH/TH+ QL/TL =0

    QL= -QHTL/TH

    Or from 1

    -Wrev= QH(TH-TL)/TH

    The efficiency of conversion of heat into work is

    HE= -Wrev/QH= (TH-TL)/TH

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    Temperature-Entropy cycle

    (Rankine Cycle) As per first law of thermo, we can present effect of P and V on a fluid, which is compressed and expanded

    in a closed cycle on PV diagram.

    Similarly T and thermal energy or entropy S can be used to represent expansion and contraction of a gas ina closed loop. The gas circulates in the heat engine absorbing heat from high T reservoir, passes through amachine to convert some of this thermal energy into work and discharging some heat to the lowtemperature reservoir. T-S diagram can be used to present this process.

    If water is taken as fluid , which is boiled at T H (path1-2) in a steam

    boiler, which is then passed through an adiabatic and reversible expander

    (turbine). The change in entropy or S is zero upon passing through turbine.

    Thus path 2-3 isentropic. Heat is then exchanged with condenser at TL in

    passing though 3-4. Here the steam is condensed into liquid water, which is

    then pumped isentropically back into the cycle through 4-1 path to the boiler.

    The pump is run by the part of the work output of the turbine. This is a basic

    Version of an ideal Rankine cycle. Here, the work done is also

    Wrev

    = -QH(T

    H-T

    L)/T

    H

    The Rankine cycle is the fundamental operating cycle of all power

    plants where an operating fluid is continuously evaporated and

    condensed.

    Entropy

    Temp.

    TTH

    TLS1 S2

    1 2

    4 3

    RefrigeratorsCarnot Cycle in Reverse

    machine designed to remove heat from low temperature region and pump it to ahigher temperature by doing some work on it.

    To maintain the temperature to lower value than surrounding, a household fridgepumps the thermal energy as heat from low temperature source to high temperaturesink and into the ambient.

    The Clausius statement of the Second Law of Thermodynamics asserts that it isimpossible to construct a device that, operating in a cycle, has no effect other thanthe transfer of heat from a cooler to a hotter body. This means that energy will notflow from cold to hot regions without outside assistance. The refrigerator and heat

    pump both satisfy the Clausius requirement of external action through theapplication of mechanical power or equivalent natural transfers of heat.

    The refrigerator cycle is thus reverse of Carnots cycle. The

    performance of this cycle is determined by heat removed from

    low temperate source divided by the work required. (QL/Wrev).

    This is termed as figure of merit.

    refrig= QL /Wrev= TL/(TH-TL)

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    Heat Pumps

    In case of a refrigerator, a low temperature reservoir is kept at a specifiedlow temperature by removing heat that leaks in from surroundings. Thesame type of device could be used to supply heat to a room attemperature higher than the outdoor temperature. The main differencebetween a refrigerator and a heat pump is in the manner of operationregarding cooling or heating. A refrigeration system cools the external fluidflowing through the evaporator, whereas a heat pump heats the externalfluid flowing through the condenser.

    The coefficient of performance of heat pump is determined by the heatdelivered to high temperate sink i.e. QH divided by the work required.

    heat pump= QH /Wrev= TH/(TH-TL)

    Heat Pump vs A/C(Function of reversing valve)